N,N′-Bis(4-chloro-3-fluorobenzylidene)ethane-1,2-diamine
نویسندگان
چکیده
The asymmetric unit of the title Schiff base compound, C(16)H(12)Cl(2)F(2)N(2), contains one half of the centrosymmetric mol-ecule. Mol-ecules related by translation along the a axis form stacks with short inter-molecular C⋯C distances of 3.429 (3) Å. The crystal packing also exhibits short inter-molecular Cl⋯F contacts of 3.087 (1) Å.
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[N,N′-Bis(4-chlorobenzyl)ethane-1,2-diamine]dichloridozinc(II)
In the title complex, [ZnCl(2)(C(16)H(18)Cl(2)N(2))], the asymmetric unit contains one mol-ecule and two half-mol-ecules, which have similar geometric parameters; in the latter two molecules each Zn atom lies on a twofold rotation axis. The environment about each Zn(II) atom is distorted tetra-hedral with coordination of two terminal Cl atoms and two N atoms of the N,N'-bis-(4-chloro-benz-yl)et...
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